Data-based estimates of the ocean carbon sink variability – First results of the Surface Ocean pCO2 Mapping intercomparison (SOCOM)

Using measurements of the surface-ocean CO2 partial pressure (pCO2) and 14 different pCO2 mapping methods recently collated by the Surface Ocean pCO2 Mapping intercomparison (SOCOM) initiative, variations in regional and global sea–air CO2 fluxes are investigated. Though the available mapping methods use widely different approaches, we find relatively consistent estimates of regional pCO2 seasonality, in line with previous estimates. In terms of interannual variability (IAV), all mapping methods estimate the largest variations to occur in the eastern equatorial Pacific. Despite considerable spread in the detailed variations, mapping methods that fit the data more closely also tend to agree more closely with each other in regional averages. Encouragingly, this includes mapping methods belonging to complementary types – taking variability either directly from the pCO2 data or indirectly from driver data via regression. From a weighted ensemble average, we find an IAV amplitude of the global sea–air CO2 flux of 0.31 PgC yr−1 (standard deviation over 1992–2009), which is larger than simulated by biogeochemical process models. From a decadal perspective, the global ocean CO2 uptake is estimated to have gradually increased since about 2000, with little decadal change prior to that. The weighted mean net global ocean CO2 sink estimated by the SOCOM ensemble is −1.75 PgC yr−1 (1992–2009), consistent within uncertainties with estimates from ocean-interior carbon data or atmospheric oxygen trend

The 2015-2016 El Nino and the Response of the Carbon Cycle: Findings from NASA's OCO-2 Mission

The El Nino Southern Oscillation (ENSO) is the most important mode of tropical climate variability on interannual to decadal time scales. Correlations between atmospheric CO2 growth rate and ENSO activity are relatively well known but the magnitude of this correlation, the contribution from tropical marine vs. terrestrial flux components, and the causal mechanisms, are poorly constrained in space and time. The launch of NASA's Orbiting Carbon Observatory-2 (OCO-2) mission in July 2014 was rather timely given the development of strong ENSO conditions over the tropical Pacific Ocean in 2015-2016. In this presentation, we will discuss how the high-density observations from OCO-2 provided us with a novel dataset to resolve the linkages between El Nino and atmospheric CO2. Along with information from in situ observations of pCO2 from NOAA's Tropical Atmosphere Ocean (TAO) project and atmospheric CO2 from the Scripps CO2 Program, and other remote-sensing missions, we are able to piece together the time dependent response of atmospheric CO2 concentrations over the Tropics. Our findings confirm the hypothesis from studies following the 1997-1998 El Nino event that an early reduction in CO2 outgassing from the tropical Pacific Ocean is later reversed by enhanced net CO2 emissions from the terrestrial biosphere. This implies that a component of the interannual variability (IAV) in the growth rate of atmospheric CO2, which has typically been used to constrain the climate sensitivity of tropical land carbon fluxes, is strongly influenced and modified by ocean fluxes during the early phase of the ENSO event. Our analyses shed further light on the understanding of the marine vs. terrestrial partitioning of tropical carbon fluxes during El Nino events, their relative contributions to the global atmospheric CO2 growth rate, and provide clues about the sensitivity of the carbon cycle to climate forcing on interannual time scales

Carbon dioxide and ocean acidification observations in UK waters. Synthesis report with a focus on 2010–2015

Key messages: 1.1 The process of ocean acidification is now relatively well-documented at the global scale as a long-term trend in the open ocean. However, short-term and spatial variability can be high. 1.2 New datasets made available since Charting Progress 2 make it possible to greatly improve the characterisation of CO2 and ocean acidification in UK waters. 3.1 Recent UK cruise data contribute to large gaps in national and global datasets. 3.2 The new UK measurements confirm that pH is highly variable, therefore it is important to measure consistently to determine any long term trends. 3.3 Over the past 30 years, North Sea pH has decreased at 0.0035±0.0014 pH units per year. 3.4 Upper ocean pH values are highest in spring, lowest in autumn. These changes reflect the seasonal cycles in photosynthesis, respiration (decomposition) and water mixing. 3.5 Carbonate saturation states are minimal in the winter, and lower in 7 more northerly, colder waters. This temperature-dependence could have implications for future warming of the seas. 3.6 Over the annual cycle, North-west European seas are net sinks of CO2. However, during late summer to autumn months, some coastal waters may be significant sources. 3.7 In seasonally-stratified waters, sea-floor organisms naturally experience lower pH and saturation states; they may therefore be more vulnerable to threshold changes. 3.8 Large pH changes (0.5 - 1.0 units) can occur in the top 1 cm of sediment; however, such effects are not well-documented. 3.9 A coupled forecast model estimates the decrease in pH trend within the North Sea to be -0.0036±0.00034 pH units per year, under a high greenhouse gas emissions scenario (RCP 8.5). 3.10 Seasonal estimates from the forecast model demonstrate areas of the North Sea that are particularly vulnerable to aragonite undersaturation

An update to the Surface Ocean CO2 Atlas (SOCAT version 2)

The Surface Ocean CO2 Atlas (SOCAT), an activity of the international marine carbon research community, provides access to synthesis and gridded fCO(2) (fugacity of carbon dioxide) products for the surface oceans. Version 2 of SOCAT is an update of the previous release (version 1) with more data (increased from 6.3 million to 10.1 million surface water fCO(2) values) and extended data coverage (from 1968-2007 to 1968-2011). The quality control criteria, while identical in both versions, have been applied more strictly in version 2 than in version 1. The SOCAT website (http://www.socat.info/) has links to quality control comments, metadata, individual data set files, and synthesis and gridded data products. Interactive online tools allow visitors to explore the richness of the data. Applications of SOCAT include process studies, quantification of the ocean carbon sink and its spatial, seasonal, year-to-year and longer-term variation, as well as initialisation or validation of ocean carbon models and coupled climate-carbon models.</p

Trends and drivers in global surface ocean pH over the past 3 decades

We report global long-term trends in surface ocean pH using a new pH data set computed by combining fCO(2) observations from the Surface Ocean CO2 Atlas (SOCAT) version 2 with surface alkalinity estimates based on temperature and salinity. Trends were determined over the periods 1981-2011 and 1991-2011 for a set of 17 biomes using a weighted linear least squares method. We observe significant decreases in surface ocean pH in similar to 70% of all biomes and a mean rate of decrease of 0.0018 +/- 0.0004 yr 1 for 1991-2011. We are not able to calculate a global trend for 19812011 because too few biomes have enough data for this. In half the biomes, the rate of change is commensurate with the trends expected based on the assumption that the surface ocean pH change is only driven by the surface ocean CO2 chemistry remaining in a transient equilibrium with the increase in atmospheric CO2. In the remaining biomes, deviations from such equilibrium may reflect that the trend of surface ocean fCO(2) is not equal to that of the atmosphere, most notably in the equatorial Pacific Ocean, or may reflect changes in the oceanic buffer (Revelle) factor. We conclude that well-planned and long-term sustained observational networks are key to reliably document the ongoing and future changes in ocean carbon chemistry due to anthropogenic forcing

The EUREC4A-Ocean/Atmosphere campaign: status

International audienceThe ocean fine scale (from the mesoscale to the submesoscale) is susceptible to impact air-sea exchange and has an integral effect on the large scale atmosphere and ocean dynamics. Many recent advances in understanding underlying processes have been obtained from modeling efforts and only few in-situ observational studies exist one of them being the EUREC4A-OA/ATOMIC campaign that was added to the EUREC4A atmospheric campaign. This experiment took place in January-February 2020 in the Northwest Tropical Atlantic Ocean with the aim to collect synchronized ocean and atmosphere data to improve our understanding of the role of fine scale processes in the internal ocean dynamics and air-sea interaction.Four oceanographic vessels, coordinated with air-borne observations and autonomous ocean platforms (underwater gliders, Saildrones, drifters), simultaneously acquired ocean and atmosphere data east of the island of Barbados and further south, up to the border of French Giuana. This way, ocean and atmospheric data was acquired in two contrasting regions: (1) the Trade wind region and (2) a region filled with mesoscale eddies. Operations allowed investigating upper ocean processes from small to mesoscale and from sub-diurnal to monthly.A variety of mesoscale eddies were crossed with diverse characteristics, ranging from shallow cyclonic and anticyclonic eddies to the deep reaching structures. Some of these eddies, and in particular North Brazil Rings, have been previously observed and described in dedicated oceanographic experiments. Nonetheless, the EUREC4A-OA/ATOMIC campaign brings in new details about the vertical structure, the dynamics and the potential impact on air-sea interactions of these mesoscale features.With the various observing platforms it was possible to sample the upper-ocean in great detail, resolving frontal scales and stratification. For example, the remnants of the Amazon plume, flowing northward along the shelf-break and being advected far offshore though NBC rings, create a rich variety of submesoscale fronts and a strong barrier layer impacting air-sea exchange of heat and momentum. The ongoing analyses on the ocean dynamics regional and local structures and specifics of air-sea interaction will be highlighted in this presentation

The EUREC4A-Ocean/Atmosphere campaign: status

International audienceThe ocean fine scale (from the mesoscale to the submesoscale) is susceptible to impact air-sea exchange and has an integral effect on the large scale atmosphere and ocean dynamics. Many recent advances in understanding underlying processes have been obtained from modeling efforts and only few in-situ observational studies exist one of them being the EUREC4A-OA/ATOMIC campaign that was added to the EUREC4A atmospheric campaign. This experiment took place in January-February 2020 in the Northwest Tropical Atlantic Ocean with the aim to collect synchronized ocean and atmosphere data to improve our understanding of the role of fine scale processes in the internal ocean dynamics and air-sea interaction.Four oceanographic vessels, coordinated with air-borne observations and autonomous ocean platforms (underwater gliders, Saildrones, drifters), simultaneously acquired ocean and atmosphere data east of the island of Barbados and further south, up to the border of French Giuana. This way, ocean and atmospheric data was acquired in two contrasting regions: (1) the Trade wind region and (2) a region filled with mesoscale eddies. Operations allowed investigating upper ocean processes from small to mesoscale and from sub-diurnal to monthly.A variety of mesoscale eddies were crossed with diverse characteristics, ranging from shallow cyclonic and anticyclonic eddies to the deep reaching structures. Some of these eddies, and in particular North Brazil Rings, have been previously observed and described in dedicated oceanographic experiments. Nonetheless, the EUREC4A-OA/ATOMIC campaign brings in new details about the vertical structure, the dynamics and the potential impact on air-sea interactions of these mesoscale features.With the various observing platforms it was possible to sample the upper-ocean in great detail, resolving frontal scales and stratification. For example, the remnants of the Amazon plume, flowing northward along the shelf-break and being advected far offshore though NBC rings, create a rich variety of submesoscale fronts and a strong barrier layer impacting air-sea exchange of heat and momentum. The ongoing analyses on the ocean dynamics regional and local structures and specifics of air-sea interaction will be highlighted in this presentation

The EUREC4A-Ocean/Atmosphere campaign: status

International audienceThe ocean fine scale (from the mesoscale to the submesoscale) is susceptible to impact air-sea exchange and has an integral effect on the large scale atmosphere and ocean dynamics. Many recent advances in understanding underlying processes have been obtained from modeling efforts and only few in-situ observational studies exist one of them being the EUREC4A-OA/ATOMIC campaign that was added to the EUREC4A atmospheric campaign. This experiment took place in January-February 2020 in the Northwest Tropical Atlantic Ocean with the aim to collect synchronized ocean and atmosphere data to improve our understanding of the role of fine scale processes in the internal ocean dynamics and air-sea interaction.Four oceanographic vessels, coordinated with air-borne observations and autonomous ocean platforms (underwater gliders, Saildrones, drifters), simultaneously acquired ocean and atmosphere data east of the island of Barbados and further south, up to the border of French Giuana. This way, ocean and atmospheric data was acquired in two contrasting regions: (1) the Trade wind region and (2) a region filled with mesoscale eddies. Operations allowed investigating upper ocean processes from small to mesoscale and from sub-diurnal to monthly.A variety of mesoscale eddies were crossed with diverse characteristics, ranging from shallow cyclonic and anticyclonic eddies to the deep reaching structures. Some of these eddies, and in particular North Brazil Rings, have been previously observed and described in dedicated oceanographic experiments. Nonetheless, the EUREC4A-OA/ATOMIC campaign brings in new details about the vertical structure, the dynamics and the potential impact on air-sea interactions of these mesoscale features.With the various observing platforms it was possible to sample the upper-ocean in great detail, resolving frontal scales and stratification. For example, the remnants of the Amazon plume, flowing northward along the shelf-break and being advected far offshore though NBC rings, create a rich variety of submesoscale fronts and a strong barrier layer impacting air-sea exchange of heat and momentum. The ongoing analyses on the ocean dynamics regional and local structures and specifics of air-sea interaction will be highlighted in this presentation

The EUREC4A-Ocean/Atmosphere campaign: status

International audienceThe ocean fine scale (from the mesoscale to the submesoscale) is susceptible to impact air-sea exchange and has an integral effect on the large scale atmosphere and ocean dynamics. Many recent advances in understanding underlying processes have been obtained from modeling efforts and only few in-situ observational studies exist one of them being the EUREC4A-OA/ATOMIC campaign that was added to the EUREC4A atmospheric campaign. This experiment took place in January-February 2020 in the Northwest Tropical Atlantic Ocean with the aim to collect synchronized ocean and atmosphere data to improve our understanding of the role of fine scale processes in the internal ocean dynamics and air-sea interaction.Four oceanographic vessels, coordinated with air-borne observations and autonomous ocean platforms (underwater gliders, Saildrones, drifters), simultaneously acquired ocean and atmosphere data east of the island of Barbados and further south, up to the border of French Giuana. This way, ocean and atmospheric data was acquired in two contrasting regions: (1) the Trade wind region and (2) a region filled with mesoscale eddies. Operations allowed investigating upper ocean processes from small to mesoscale and from sub-diurnal to monthly.A variety of mesoscale eddies were crossed with diverse characteristics, ranging from shallow cyclonic and anticyclonic eddies to the deep reaching structures. Some of these eddies, and in particular North Brazil Rings, have been previously observed and described in dedicated oceanographic experiments. Nonetheless, the EUREC4A-OA/ATOMIC campaign brings in new details about the vertical structure, the dynamics and the potential impact on air-sea interactions of these mesoscale features.With the various observing platforms it was possible to sample the upper-ocean in great detail, resolving frontal scales and stratification. For example, the remnants of the Amazon plume, flowing northward along the shelf-break and being advected far offshore though NBC rings, create a rich variety of submesoscale fronts and a strong barrier layer impacting air-sea exchange of heat and momentum. The ongoing analyses on the ocean dynamics regional and local structures and specifics of air-sea interaction will be highlighted in this presentation